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Risk Management Strategy for Road Salts

1.0 Issue and Background
2.0 Concerns / Need for Action
3.0 Exposure Sources
4.0 Considerations
5.0 Objectives
6.0 Risk Management Instruments
7.0 Implementation
8.0 Proposed Consultation Approach
9.0 Next Steps / Timeline
Annex 1 Draft Summary of Assessment-Based Targets for Road Salts

1.0

Issue And Background

The Priority Substances List Assessment Report for Road Salts was published on December 1, 2001. The report concluded that Road Salts that contain inorganic chloride salts with or without ferrocyanide salts have adverse impacts on the environment and are therefore toxic under Section 64(a) and (b) of the Canadian Environmental Protection Act, 1999 (CEPA 1999). Since Road Salts are neither persistent nor bioaccumulative, they have been categorized as Track 2 under the Toxic Substances Management Policy.

The Road Salt assessment covered the chloride salts: sodium chloride (NaCl), calcium chloride (CaCl2), magnesium chloride (MgCl2), potassium chloride (KCl), brines used in road deicing/anti-icing, dust suppression, the salt portion of abrasive mixtures and additives commonly used in road salts (ferrocyanides).

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2.0

Concerns / Need For Action

It is estimated that approximately five million tonnes of chloride salts are released into the Canadian environment each year. This salt enters the surface water, soil and groundwater and there is clear indication of environmental impact.

The assessment documented adverse effects on soil properties, roadside vegetation, wildlife, groundwater, aquatic habitat, and surface water.

The following areas of concern have been identified in the assessment.

  • Surface and groundwaters: Road Salt contamination of surface and groundwater is a concern in areas of high use on roadways and along major expressways as well as near point contamination from salt depots. There is clear indication of environmental impact in specific areas. Distance from sensitive areas will increase the time to reach concentrations of concerns. Ultimately all high use areas will be of concern. Many of the civil liability claims from property owners against transport authorities are related to contamination of well water from salt released into groundwater.

  • Soils Characteristics - Abiotic Effects: Sodium may displace other metals from the soil depending on soil conditions, clay content and exchangeable sodium ratio (ESR). Areas with highest impact will be where there is a high percentage clay content, and high ESR and low precipitation. Hot spots include southern Ontario, southern Quebec, and Alberta.

  • Vegetation: Plants can be exposed through the soil, air (salt mists from the road) and runoff water. Salt can be taken up by vegetation roots or deposited directly on foliage. In certain sensitive agricultural areas (e.g. orchard areas), contamination from road salt application has affected nearby crops and trees. In water drainage, salt is easily transported to surface waters such as creeks, rivers, lakes or oceans and can affect various populations of aquatic species.

  • Sodium ferrocyanide: This chemical is used as an anti-caking agent. In aqueous solution when exposed to sun light, it breaks down into cyanide ions. Although only present in small amounts, it may be toxic to the aquatic environment.

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3.0

Exposure Sources

The following sources have been identified:

  • local contamination from improper salt storage and snow disposal resulting in contamination of groundwater and the discharge to surface water of high concentrations of chloride salts
  • large scale contamination from general repeated heavy use in urban areas with high road density, examples are regions of southern Ontario, Quebec and the Atlantic provinces which have the highest rate of salt use
  • roadway application, salt storage and snow disposal in close proximity to sensitive areas such as wetlands, endangered species, surface waters, groundwater, park land, etc.

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4.0

Considerations

  1. There are no federal regulations in Canada which directly govern levels of salt use, or salt concentrations in various environmental media. The only relevant national environmental standards, which relate indirectly to road salt in the environment, are the Guidelines for Canadian Drinking Water Quality, March 2001. The aesthetic objective (taste) is a maximum of 200 ppm sodium and 250 ppm chloride.

  2. Municipalities use 50-65% of road salts, provinces use 30-45% and the private sector (parking lots, private roads etc.) uses 5-10%.

  3. The use of road salt along with plowing is recognized as the most efficient method of keeping roads and highways clear and safe in hazardous winter conditions.

  4. The industry provides significant indirect benefits to the economy, including maintaining economic activity, reducing accidents, and reducing fuel use in storm events.

  5. Programs are in place in the northern U.S. to promote more efficient use of sand/salt/de-icing chemicals. These programs began with reducing sand and improving salt use and have moved to pre-wetting and anti-icing. Extensive work was carried out in Sweden and Finland to identify and protect sensitive aquifers through salt management practices.

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5.0

Objectives

Environmental Objective

Environmental objectives are proposed for surface water, vegetation, soils, wildlife, groundwater, and ferrocyanides based on the assessment report. (Please refer to Annex I)

Risk Management Objectives

Environment Canada is considering a best management practices approach that will build on existing work that has been done by the Transportation Association of Canada (TAC) in its Salt Management Guide and Salt Management Action Plan.

  1. Salt Storage: (Best Management Practices, significant reductions of impacts)
    • No further deterioration of site and for new sites no uncontrolled releases.

  2. Snow Disposal: (Best Management Practices, significant reductions of impacts)
    • Effective practices reducing chlorides and other contaminants to acceptable levels.

  3. Road Salt Use: General Areas (Best Management Practices, reductions of salt use in average winter)
    • New technologies for general use have shown significant reductions while improving road safety (in the area of 20-30%), however, the amount used in a season depends on the weather and severity of the winter. This reduction is supported by several studies.

  4. Road Salt Use in Sensitive Areas (Definition of a sensitive area will be established in consultation with Provinces)
    • Establish what constitutes a sensitive area.
    • Identify approaches that can be used in addition to best management practices, such as use of alternative chemicals.

  5. Ferrocyanide
    • Significant reduction or substitution of ferrocyanide salts.

  6. Monitoring and Reporting
    • Establish a regular monitoring and reporting program to measure the implementation of best management practices and effects over a 5 year period. Determine if the risk management objectives are being met and the recommended controls are effective and reevaluate accordingly.

  7. Consideration of alternative anti-icing / de-icing agents
    • Chemical alternatives to sodium chloride used in winter road maintenance and associated technical, environmental and economic issues.

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6.0

Risk Management Instruments

The following factors were considered in the choice of a management instrument to achieve the risk management objectives:

  • The management instruments must ensure the risk management objectives are met and road safety is not compromised.
  • Expected environmental improvement from the achievement of the proposed risk management objectives must be demonstrated.
  • Monitoring of the objective to measure progress
  • Cost effectiveness of the measures
  • Management instruments must allow a flexible approach based on local situations

The screening analysis has shown the most promising instruments for addressing the environmental concerns with salt use on roads (General and Near Sensitive Areas), salt storage, and snow disposal are Environmental Performance Agreements (EPAs), Pollution Prevention Plans (P2 Plans) and CEPA Guidelines or Codes of Practice. EPAs or P2 plans would be difficult to implement considering the number of users. Our approach is to build on work done by TAC and road authorities with the concept of salt management plans to implement best management practices described in a code or guideline.

For ferrocyanides, the screening has shown that EPAs, Input Controls and Pollution Prevention Plans are the most promising instruments. Our approach is to propose an EPA or use P2 plans depending on the level of cooperation that will be demonstrated by the salt producers.

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7.0

Implementation

As required under CEPA 1999, a preventive or control instrument for road salts must be proposed no later than December 1, 2003. The proposed CEPA Code of Practice or Guideline is targeted for publication in the Canada Gazette during November, 2003 and will be followed by a 60-day public comment period.

A compliance promotion strategy for this code of practice or guideline will be developed. The risk manager and regional counterparts will work together to provide information to the target community in order to promote compliance to this code of practice / guideline.

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8.0

Proposed Consultation Approach

  1. Create an advisory group that will provide comments on consultation process.

  2. Identify Stakeholders and establish a Working/Consultation Group
    • Primary stakeholders - The involvement of the provinces and municipalities in the development and implementation of a control option is essential because they are in the best position to determine appropriate and effective risk management.
    • The road salt and alternative Industry, Associations (i.e. Federation of Canadian Municipalities, Canadian Public Works Association and TAC) and commercial users,
    • Stakeholders related to the indirect benefits of salt use (consumer group, health and safety group, etc.)
    • ENGOs
    • Targeting 35 to 40 member working group


  3. Hold Stakeholder Meetings
    • expected: Meet regularly over the next year to define specifics and establish a balanced approach
    • use of a facilitator


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9.0

Next Steps / Timeline

Having published the Ministers' final decision under subsection 77(6) of CEPA 1999, Environment Canada has two years to develop control measures to reduce the impact of road salts on the environment and a further 18 months to finalize them. Environment Canada will form a working group to advise on selection and development of measures and begin stakeholder meetings in the winter (2002). The objective is to publish proposed control measures in the Canada Gazette, Part 1 by December 1, 2003.

Revised 3 May, 2002.

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Item Specific Actions for Road Salt Management Goal / Target Status

1

Phase 1 Report, Socio-Economic Background and options study on the Canadian Salt Industry

October, 1999

Complete

2 Contract a Phase 2 Qualitative Management Option Study on Road Salt to:
  • assess risk management options for source(s) of concern related to the risk management of Road Salt based on established environmental objective(s) and criteria;
  • recommend a preferred risk management option(s)
  • identify what controls/guidelines/codes already exist at the Provincial and Municipal level
  • establish who are the authorities at these levels (the main players)
  • develop use studies (case studies municipalities using and not using salt etc.)
  • asses level of information exchange between (Federal/Provincial/Municipal)
  • identify the network related to road salt and snow removal
  • estimate costs/damages or benefits related to salt use
June, 2001 Complete
3 Identify Stakeholders
  • Primary stakeholders - Provinces and Municipalities - plan to get them informed and on-board
  • The Road Salt and alternative Industry/Associations including TAC
  • ENGOs
February, 2002 Complete
4 Beginning of Stakeholder Meetings
   Stakeholder Meetings presenting:
  • Environmental Objectives, possible controls and timelines
April, 2002 Complete
5 Conclusion on Management Instruments December, 2002  
6 Contract a Quantitative Management Option Cost/Benefit Analysis Study to:
  • Provide design and implementation details and an assessment of the impact of the recommended risk management option(s) and implementation plan. etc.
January, 2003  
7 Develop selected Instruments Dec 02 to Dec 03  
8 Publish proposed Instruments December, 2003  
9 Publish Instruments May, 2005  

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Annex 1 Draft Summary of Assessment-Based Targets for Road Salts
Media Assessment-Based Targets Other Guidance
  Descriptive Outline of Assessment-Based Target Quantitative  
Surface water The assessment-based target for the protection of surface water is to:
  • ensure that concentrations of chlorides do not exceed levels that may result in adverse effects on growth, reproduction or survival in the short term.
Short term

If continuous or near-continuous monitoring is carried out, use the U.S. EPA objectives for short term concentrations:

The 1 hour average chloride concentration does not exceed 860 mg/L more than once every 3 years on average.

For occasional monitoring:
  • 140 mg Cl/L for a 96-h LC50 for Ceriodaphnia dubia using a safety factor of 10.
  • Exposure to such high lethal concentrations would most likely be associated with poorly managed salt storage depots, inappropriately placed snow dumps on wetland areas, roadside ditches in areas of high use, contaminated groundwater springs and small watercourses in heavily populated urban areas (e.g., Metropolitan Toronto) that have a dense network of highways and road salt application.

  • Chloride concentrations at these levels have been observed in a variety of urban creeks, streams and lakes, although primarily in highly populated areas and small water bodies near highways with high use. Such levels are also expected to occur in the vicinity of poorly managed road salt storage depots and in inappropriately placed snow dumps, e.g., on wetlands, in small ponds, near headwater creeks and near contaminated groundwater-fed creeks and near contaminated groundwater-fed springs. Aquatic ecosystems experiencing such chloride levels are expected to be impaired.

  • The CCME guideline for chlorides for human health and aquatic organisms is 250 mg/L.. For irrigation waters, sensitive plants should not be irrigated with waters >100 mg/L Cl while tolerant plants can be irrigated with water up to 700 mg/L Cl.

  • The province of Quebec has adopted the EPA water quality guidelines. In Quebec, aquatic life suffer acute toxicity at minimum chloride concentrations of 860 mg/L. Chronic toxicity occurs at chloride concentrations of 230 mg/L and any increases must not exceed 10 mg/L.

  • The U.S. EPA developed water quality guidelines for chloride and concluded that, except possibly where a locally important species is very sensitive, freshwater organisms and their uses should not be affected unacceptably if:

    The 4-day average concentration of chloride, when associated with sodium, does not exceed 230 mg/L more than once every 3 years on average; The 1 hour average chloride concentration does not exceed 860 mg/L more than once every 3 years on average.
They noted that these criteria will not be adequately protective when the chloride is associated with K, Ca or Mg, and that because animals have a narrow range of acute sensitivities to chloride, excursions above this range might affect a substantial number of species.
  • ensure that concentrations of chlorides do not exceed levels that may result in adverse effects on growth, reproduction or survival in the long term.
Long term:

If continuous or near-continuous monitoring is carried out, use the U.S. EPA objectives for short term concentrations:

The 4-day average concentration of chloride, when associated with sodium, does not exceed 230 mg/L more than once every 3 years on average;

For occasional monitoring:
  • 35 mg Cl/L based on a 33-d LOEC of 352 mg Cl/L for reproduction in Pimephales promelas using a safety factor of 10.

  • Major shifts in diatom and chrysophyte assemblages were associated with relatively small changes in salinity (i.e., from ca. 12-235 mg/L Cl and ca. 20-387 mg/L NaCl).

  • Meromictic conditions have developed in lakes where the salt concentrations in the monimolimnion were 58.4 mg/L Na and 103.7 mg/L Cl. Bottom waters became anoxic in a lake in the NE US when chloride concentrations increased from 19 mg/L to 260 mg/L chloride.
  • ensure that the seasonal mixing that occurs in surface water bodies is not impaired.
  • Meromictic conditions have developed in lakes where the salt concentrations in the monimolimnion were 58.4 mg/L Na and 103.7 mg/L Cl. Bottom waters became anoxic in a lake in the NE US when chloride concentrations increased from 19 mg/L to 260 mg/L chloride.
Vegetation The environmental objective for the protection of vegetation is to:
  • ensure that concentrations of sodium and chloride in soil do not exceed levels that may result in effects on growth, reproduction or survival.
  • Harm to salt-sensitive plants may start to appear at concentrations derived from experimental data of: 67.5 sodium and 215 ppm chloride.

  • For less sensitive plants, effects start to show up at concentrations of about 300 ppm sodium and 1500 ppm chloride.

  • In the field, moderate damage to plants has sometimes been found at soil concentrations of about 16 ppm sodium and 30 ppm chloride. Therefore, in relatively pristine areas where natural salt concentrations are low, it would probably be desirable to keep sodium and chloride concentrations below these lower levels. Where it is known that plants are salt tolerant or where natural salt concentrations are higher, then higher levels could be allowed.
  • Zone of impact on susceptible plants extends up to 80 m from the edge of multi-lane highways and up to 35 m from two-lane highways.
  • ensure that native species are not displaced by halophytic species along roadsides in Ontario. Halophytic species were spreading naturally along highways in response to the use of de-icing salts and the decline of non-adapted planted vegetation. These included areas within the engineered right-of-way, within the planted right-of-way and outside the right-of-way.
   
Soils abiotic
  • The environmental objective for the protection of soil is to protect the soil integrity. This involves ensuring that application of road salts does not result in deleterious effects on physical and chemical parameters including soil structural stability, soil dispersion, soil permeability, soil swelling and crusting, soil electrical conductivity and soil osmotic potential.
  • It is assumed that an environmental objective developed for vegetation will be protective enough for soils.
   
Soils biota The environmental objective for the protection of soil biota is to:
  • ensure that concentrations of sodium and chloride do not exceed levels that may result in effects on growth, reproduction and survival.
  • Sensitive soil bacterium are moderately inhibited by sodium chloride at concentrations as low as 150 mg sodium chloride/L (corresponding to approximately 60 mg sodium/L and 90 mg chloride/L). Soil nitrification can be significantly reduced at a sodium chloride concentration of 250 mg/kg (approximately 100 mg sodium/kg and 150 mg chloride/kg).
  • Soil concentrations of sodium exceeding 60 mg/kg have been reported within about 30 m from the edges of roads in Canada. Soil concentrations of chloride exceeding 200 mg/kg have been reported within about 200 m from the edges of roads in Canada.
Wildlife The environmental objective for the protection of wildlife is to:
  • ensure that collisions between birds and mammals, and cars are minimized.
  • ensure that toxicity to birds as a result of ingestion of road salts is minimized.
  • Road salts may poison birds directly or increase the vulnerability of birds to car strikes by causing impairment. The CTV (breach of sodium homeostasis) for a model 28 g house sparrow is 266 mg/kg-bw. The number of salt particles that need to be ingested by a bird to achieve this CTV is 0.47 of a 2.4-mm-diameter spherical salt particle. Mortality was recorded at a CTV of 1500 mg/kg-bw which corresponds to 2.6 particles of 2.4-mm-diameter spherical salt particles.

  • Any reduction in salt application rates would probably result in fewer birds and mammals being attracted to roadways, and therefore few collisions between birds and mammals.

  • Where possible, the use of particulate salt should be curtailed, so that salt particles are not taken up as grit by birds. Brines may be the solution.

 
Ferrocyanides
  • The environmental objective is to ensure that the release of sodium ferrocyanide will not result in effects on survival in microorganisms, plants, invertebrates and vertebrates, in both terrestrial and aquatic organisms.

  • The ferrocyanide anion is of low toxicity in the complexed form but in solution it undergoes photodecomposition, resulting in the release of cyanide ion and its subsequent hydrolysis to hydrogen cyanide.

  • For aquatic microorganisms CTV (µg/L), the bacterium Pseudomonas putida had the lowest concentration showing a significant adverse effect of growth inhibition a 1µg/L during 16 hours exposure to HCN. No application factor was used.

  • For aquatic vertebrates, the assessment based target for water could be 1 µg CN/L, based on fish spawning inhibition at 5 and 5.2 µg CN/L, using an application factor of 5.

  • For soil, the target could be 0.8 mg CN/kg soil, based on a 14-d LC25 of 4 mg CN/kg soil for Eisenia fetida, using a safety factor of 5.

  • The IC25 for seedling emergence of radishes was 1.2 mg CN/kg soil, so the proposed target should be protective of plants as well as soil-dwelling animals.

  • The Final Chronic Value for free cyanide (expressed as CN) established by the US EPA is 5.221 µg/L. This is equivalent to a HCN concentration of 5.422 µg/L.

  • Based on the highest annual road salt application rate, the estimated free cyanide concentration in run-off water is 39 mg/L. The measured total cyanide concentration in meltwater runoff is 41.5 mg/L.

  • The Canadian Council of Resource and Environment Ministers (CCREM) has established that, for the protection of aquatic life, the concentrations of cyanide in freshwater should not exceed 5 µg (CN-)/L as free cyanide.
The following paragraphs refer to modeling undertaken for the Quebec-Windsor corridor.
  • Aquatic microorganisms: Two of five aquatic microorganisms would be adversely affected. Pseudomonas putida would be adversely affected in 100% of modeled exposures. Microregma heterostoma would be affected adversely in as many as 60% of cases in the municipality of highest use.
  • Aquatic plants: potential for moderate effects at certain times for sensitive species. The most sensitive alga identified could be adversely affected in 16-28% of possible exposure scenarios, with a value as high as 82% in the municipality with highest use. There is a potential for moderate effects at certain times for certain sensitive species, with lower levels of risk for most aquatic plants at most sites and times.
  • Aquatic invertebrates: Adverse effects on the doughboy scallop may occur on as many as 34% of exposures during April in Quebec City. For municipalities with highest use, adverse effects could occur for 88% of occurrences. Significant exposure of sensitive species may occur.
  • Aquatic vertebrates: highest potential for significant exposures. 96-h LC50 for rainbow trout of 17µg/L. Probability of occurrence is 53, 27 and 25% for January and 67, 36 and 34% in April within the Quebec City to Windsor corridor.
Groundwater The environmental objective for the protection of groundwater is to:
  • ensure that concentrations of chloride do not exceed levels that may result in effects on growth, reproduction and survival of groundwater organisms.
  • ensure that elevated concentrations of groundwater containing chloride that emerges into springs and surface water, do not exceed levels that may result in effects on growth, reproduction and survival of surface water organisms.
  • Groundwater containing NaCl will upwell as springs discharging from aquifers.
  • Depending on hydrogeological conditions, discharge of chloride may take 5 to >200 years.
  • The short and long term values presented for the surface water biota should be protective of groundwater biota.
Ensure that awareness is made of the potentially extended length of time required for steady state to be achieved and this is taken into account when determining applications rates of chloride.
   

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