Global Warming Potentials

All greenhouse gases (GHGs) are not equal. In fact, each greenhouse gas has a unique atmospheric lifetime and heat-trapping potential.

The concept of a Global Warming Potential (GWP) has been developed to allow the comparison of the ability of each greenhouse gas to trap heat in the atmosphere relative to carbon dioxide (CO2) over a specified time horizon. Often, greenhouse gas emissions are calculated in terms of how much CO2 would be required to produce a similar warming effect oven the chosen time horizon. This is called the carbon dioxide equivalent (CO2 eq) value and is calculated by multiplying the amount of gas by its associated GWP.

Consistent with Decision 2/CP.3 the 100-year GWPs, provided by the Intergovernmental Panel on Climate Change (IPCC) in its Second Assessment Report (SAR) are required for inventory reporting under the United Nations Framework Convention on Climate Change (UNFCCC) and for the 1st commitment period under the Kyoto Protocol. These GWPs are also required for facility greenhouse gas reporting, under S.46 of the Canadian Environmental Protection Act.

The IPCC conducts periodic assessments on human induced climate change as the science evolves over time. The latest assessment resulted in updated GWPs, which were presented in the Fourth Assessment Report (AR4) published in 2007.  However, the UNFCCC has not made any recommendations on which GWPs should be applied.

Global warming potentials for greenhouse gases

IPCC Global Warming Potentials - 100-Year Time Horizon
Greenhouse GasFormulaSecond Assessment Report1Fourth Assessment Report2
Carbon dioxideCO211
MethaneCH42125
Nitrous oxideN2O310298
Sulphur hexafluorideSF623 90022 800
Hydrofluorocarbons (HFCs)
HFC-23CHF311 70014 800
HFC-32CH2F2650675
HFC-41CH3F150 
HFC-43-10meeC5H2F101 3001 640
HFC-125C2HF52 8003 500
HFC-134C2H2F4
(Structure: CHF2CHF2)
1 000 
HFC-134aC2H2F4
(Structure: CH2FCF3)
1 3001 430
HFC-143C2H3F3
(Structure: CHF2CH2F)
300 
HFC-143aC2H3F3
(Structure: CF3CH3)
3 8004 470
HFC-152aC2H4F2
(Structure: CH3CHF2)
140124
HFC-227eaC3HF72 9003 220
HFC-236faC3H2F66 3009 810
HFC-245caC3H3F5560 
Perfluorocarbons (PFCs)
PerfluoromethaneCF46 5007 390
PerfluoroethaneC2F69 20012 200
PerfluoropropaneC3F87 000 
PerfluorobutaneC4F107 0008 860
Perfluorocyclobutanec-C4F88 700 
PerfluoropentaneC5F127 500 
PerfluorohexaneC6F147 4009 300

1 IPCC Second Assessment Report (1996)
2 IPCC Fourth Assessment Report (2007)